Hot molecules in radical combination

Author:

Bell T. N.,Zucker U. F.

Abstract

1:1 Difluoroethylene is formed when CF3 radicals react with alkyl silanes. We propose that the olefin results from the rearrangement and decomposition of a hot molecule arising from radical recombination[Formula: see text]

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Inorganic Chemistry of Hexafluoroacetone;Advances in Inorganic Chemistry;1986

2. An evaluation of the kinetic data for hydrogen abstraction from silanes in the gas phase;Reviews of Chemical Intermediates;1978-10

3. Kinetics of radical exchange in the reaction of CF3 radicals with tin tetramethyl;Canadian Journal of Chemistry;1976-05-15

4. Kinetics of the Thermal Decomposition of β-Trifluoroethylsilanes and Hot Molecule Kinetics of (CF3CH2SiF3);Canadian Journal of Chemistry;1974-09-15

5. Gas Kinetics;Annual Review of Physical Chemistry;1972-10

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