Les équations cinétiques pour les systèmes réactifs. Initiation photochimique et thermique. Les coefficients de vitesse

Abstract

In a previous publication a method was developed for obtaining kinetic equations for a reacting system. In this publication that method is applied to a system [Formula: see text] whose initiation is a photodissociation. The reactive Hamiltonian has been found through Tani's generalized transformation. The generalized kinetic equation has been used. The cluster expansion of the collision superoperator has been obtained from the cluster expansion of the resolvent superoperator, by assuming that collisions are instantaneous. The generalized Boltzmann equations have been obtained. From the kinetic equations we have found the master equations and from them the rate coefficients have been identified.