Abstract
Reaction of mercury(II) iodide with tetraethylthiuramdisulfide in chloroform and ethanol mixed solvent produced bis(iodo-N,N-diethyldithiocarbamatomercury(II)) and diiodotetraethylthiuramdisulfidemercury(II), HgI2.TETD. The crystal of HgI2.TETD is orthorhombic with a = 13.101(9), b = 13.999(9), c = 22.742(15) Å; space group Pbca. The structure was solved with 1960 observed reflections measured by a G.E. XRD-6 diffractometer. The final R factor was 0.064. The mercury atom is four-coordinated with two identical Hg—I distances of 2.668(1) Å and two Hg—S distances of 2.670(7) and 2.737(7) Å. The coordination is tetrahedral.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
15 articles.
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