Synthesis of 4-O-β-D-Glucopyranosyl-L-rhamnopyranose-Reference-Cited by-同舟云学术

Synthesis of 4-O-β-D-Glucopyranosyl-L-rhamnopyranose

Published:1972-10-15 Issue:20 Volume:50 Page:3373-3378
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Bebault G. M.,Dutton G. G. S.

Abstract

4-O-(β-D-Glucopyranosyl)-L-rhamnose (scillabiose) has been synthesized in 55% yield by condensation of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide with methyl 2,3-O-isopropylidene-α-L-rhamnopyranoside using mercuric cyanide in acetonitrile (Helferich reaction). The disaccharide and the derived alditol are both syrups but each forms a crystalline peracetate. A convenient synthesis of 1-deoxy-D-erythritol is described.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v72-539

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