Exploration of the α-effect by substitution on hydroxylamine anions. I. Effects of alkyl- and fluoroalkylation-Reference-Cited by-同舟云学术

Exploration of the α-effect by substitution on hydroxylamine anions. I. Effects of alkyl- and fluoroalkylation

Published:2014-04 Issue:4 Volume:92 Page:346-353
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Afzal D.¹,Fountain K.R.¹

Affiliation:

1. Chemistry Department, Truman University, Kirksville, MO 63501, USA.

Abstract

Many explanations for the α-effect have been suggested. Most are simple models conjecturing various sources affecting the nucleophilic behavior. This paper provides a comprehensive study of electronic effects using the single α-atom lone electron pair of substituted hydroxyl amine anions. This substituent scheme shows that the interaction of this lone pair with the negatively charged oxygen atom is an important indicator of reactivity.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2013-0246

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