Synthesis and structures of monomeric group 14 triols and their reactivity-Reference-Cited by-同舟云学术

Synthesis and structures of monomeric group 14 triols and their reactivity

Published:2014-06 Issue:6 Volume:92 Page:542-548
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Pop Lucian-Cristian¹²,Kurokawa Nobuaki¹,Ebata Hiroaki¹,Tomizawa Katsuya¹,Tajima Tomoyuki¹,Ikeda Masatoshi¹,Yoshioka Michikazu¹,Biesemans Monique³,Willem Rudolph³,Minoura Mao⁴,Saito Masaichi¹

Affiliation:

1. Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama 338-8570, Japan.

2. Babes-Bolyai University, 1, Kogalniceanu Street, Cluj-Napoca, Romania.

3. High Resolution NMR Centre, Department of Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2 B-1050, Brussels, Belgium.

4. Department of Chemistry, College of Science, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan.

Abstract

The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and -germane. The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy. The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn–O–Si–O–Sn linkages in the molecule. All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2013-0496

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