The Solvolysis of 5,5-Diphenylcyclononyl p-Toluenesulfonate. A Reinvestigation
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Published:1971-10-15
Issue:20
Volume:49
Page:3243-3248
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ISSN:0008-4042
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Container-title:Canadian Journal of Chemistry
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language:en
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Short-container-title:Can. J. Chem.
Author:
McIntosh John M.,Miskow M. H.,Wood Gordon
Abstract
Reinvestigation of the acetolysis of 5,5-diphenylcyclononyl tosylate (1) has confirmed the absence of any transannular processes and deamination of the corresponding amine 16 gave a similar resuit. Trifluoroacetolysis of 1 caused extensive transannular hydride migration but no phenyl migration. The former may be due to secondary acid-catalyzed rearrangements.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
1 articles.
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