High resolution studies of magnetic optical activity in the 3A2–lA1 system of formaldehyde

Author:

Brown J. M.,Buckingham A. D.,Ramsay D. A.

Abstract

Magnetic rotation spectra of the 3A21A1 system of formaldehyde have been photographed with high resolving power; the 1+–0 band has been studied in detail throughout its rotational fine structure. The magnetic circular dichroism (MCD) and birefringence (MCB) of this band have also been recorded. The results have been interpreted using the theory of Buckingham and Stephens and satisfactory agreement found. The magnetic optical activity arises primarily from A terms although some features which can be attributed to B terms have been identified.

Publisher

Canadian Science Publishing

Subject

General Physics and Astronomy

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1. Amyand David Buckingham 1930–2021;Historical Records of Australian Science;2022-01-18

2. Amyand David Buckingham. 28 January 1930—4 February 2021;Biographical Memoirs of Fellows of the Royal Society;2021-12-08

3. Velocity Modulation Spectroscopy of Ions;Chemical Reviews;2005-08-13

4. Molecular Spectroscopy;digital Encyclopedia of Applied Physics;2003-04-15

5. Optical heterodyne velocity modulation spectroscopy enhanced by a magnetic rotation effect;Chemical Physics Letters;1999-07

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