Author:
Perrin Patrick M.,Collin Guy J.
Abstract
Photolysis of 1-pentene molecules at 8.4 eV (xenon photolysis) and 10.0 eV (krypton photolysis) was studied. Excited molecules decompose to produce mainly ethylene, propadiene, 1,3-butadiene, acetylene, and other minor products. Hydrogen atoms add to the double bond of the monomer and the resulting excited pentyl radical decomposes at low pressure (P < 1 Torr) into propene and ethyl radical. Isomerization of excited 1-pentene molecules is unimportant at these energies.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
10 articles.
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