Author:
MacDonald Helen H. J.,Crawford Robert J.
Abstract
Optically active trans-2-phenyl-3-p-tolyloxirane and cis-2-phenyl-3-p-tolyloxirane were synthesized and the kinetics of their racemization and geometrical isomerization were studied.The slower rate of racemization of the cis-isomer compared with that of the trans is attributed to the conrotatory opening of the oxirane ring.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
36 articles.
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