Author:
Fong Harvey Owen,Hardstaff William Rayne,Kay Denis George,Langler Richard Francis,Morse Richard Herman,Sandoval Deig-Nevy
Abstract
A series of γ-sulfone sulfonyl chlorides undergo a novel reduction upon reaction with lithium aluminum hydride to furnish the corresponding ethyl sulfones. The reactions appear to proceed in an SN2 fashion with the chlorosulfonyl moiety functioning as the leaving group. In general sulfonyl chlorides furnish mercaptans as hydride reduction products.A novel two-phase hydrolysis is shown to convert a thiol ester to a symmetric sulfide which involves hydrolysis and an SN2 displacement in the aqueous phase.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
35 articles.
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