Author:
Willis C.,Boyd A. W.,Bindner P. E.
Abstract
The yields of N2, O2, NO, and O3 have been measured from the Febetron radiolysis of N2O–O2 mixtures with and without SF6. A mechanism consistent with the yields from 0–100% O2 and with known ionic abundances and reaction rate data has been derived. The major features of this mechanism are both dissociative neutralization of N2O+ and excitation of N2O to give N2(X1Σ) and O(1D) and smaller amounts of N2(B3Π) and O(3P). The large yields of NO and N2 observed are mainly due to reaction of O(1D) with N2O to give both N2 and O2 and NO.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
12 articles.
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