Author:
Lee Choi Chuck,Demchuk Ken J.,Sutherland Ronald G.
Abstract
From ligand exchange reactions between ferrocene and pyrene, carried out in the presence of AlCl3–Al, the η6-pyrene-η5-cyclopentadienyliron, η6-4,5-dihydropyrene-η5-cyclopentadienyliron, and η6-4,5,9,10-tetrahydropyrene-η5-cyclopentadienyliron monocations (2, 3, and 4, respectively) as well as the η6-pyrene-trans-bis-η5-cyclopentadienyliron and η6-4,5,9,10- tetrahydropyrene-trans-bis-η5-cyclopentadienyliron dications (5 and 7, respectively) were isolated and identified. A possible mechanism for the partial hydrogenation of the pyrene ligand is discussed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
26 articles.
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