Abstract
1-Acetoxy-1,3-butadiene was prepared by the reaction of crotonaldehyde with acetic anhydride in the presence of potassium or sodium acetate. The product was found to consist of two forms which, from their physical properties and infrared spectra, appear to be cis and trans. Mass and ultraviolet spectra, and methods of analysis are also reported. The cis form was found to be a substantially stronger inhibitor than the trans in the bulk polymerization of vinyl acetate using benzoyl peroxide as catalyst.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
14 articles.
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