A short formal total synthesis of (±)-hirsutic acid-Reference-Cited by-同舟云学术

A short formal total synthesis of (±)-hirsutic acid

Published:2012-11 Issue:11 Volume:90 Page:927-931
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Revol Guillaume¹,Fuchs Christian¹,Zard Samir Z.¹

Affiliation:

1. Laboratoire de Synthèse Organique, CNRS UMR 7652, École Polytechnique, 91128, Palaiseau, France.

Abstract

A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v2012-037

Reference43 articles.

1. The structure and chemistry of hirsutic acid

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