Abstract
The radiolysis of the isotopic mixture: iso-C4H8 + iso-C4D8 shows that, at 48 Torr pressure, about 40% of isobutane is formed in an ion–molecule reaction between isobutyl ion and the monomer. Half of the propene produced in radiolysis is formed in ion–molecule reactions, the H− transfer reaction to C3H5+ ion being the most important process. Small fractions of CH4, C2H2, C2H4, allene, and propyne are also formed in ionic processes, but the main part results from unimolecular decomposition processes of the excited isobutylene.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
6 articles.
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