Abstract
Excess volumes and viscosities of binary liquid mixtures of N-methylpyrrolidinone – tetrahydrofuran and propylene carbonate – acetonitrile are measured and examined in the light of empirical theories such as absolute rate, free volume, and regular solution theories. It is shown that non-ideality arises due to (a) shape factors, (b) molecular interaction, and that the two properties, excess volume and viscosity, illustrate these two aspects of non-ideality.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
19 articles.
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