Author:
Preti Carlo,Tosi Giuseppe
Abstract
Complexes of 2-mercaptobenzoxazole (mbo) with Zn(II), Cd(II), Hg(II), Cu(I), Ag(I), Au(I), Ni(II), Pd(II), Pt(II), Co(II), Rh(III), and Ir(III) were prepared and characterized. Their structures have been assigned on the basis of chemical analysis, ir and far ir spectroscopy, electronic spectra, and magnetic susceptibility measurements. The ligand always bonds through both the sulphur and the nitrogen heteroatoms. The ligand field parameters have been evaluated and are in keeping with the proposed structures confirming the presence of MS2N2 and MS3N3 chromophores.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
28 articles.
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