A Revision of the Stereochemistry of Lactucin

Author:

Bachelor Frank William,Itô Shô

Abstract

On the basis of circular dichroism measurements on lactucin, hydroxyachillin, and acetoxyachillin the stereochemistry of the C-5 hydrogen has been revised to the 5α configuration. The reasons for the former erroneous assignment are reexamined and the structures of several hexahydrolactucin derivatives are reinterpreted.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 13 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Human–Environment Interactions – Taste;Comprehensive Natural Products II;2010

2. Three new sesquiterpene hemiacetals fromAchillea vermicularis;Natural Product Research;2005-09

3. Thermally Induced Flavor Compounds;HortScience;2000-10

4. Lactuca virosa L. (Bitter Lettuce): In Vitro Culture and Production of Sesquiterpene Lactones;Medicinal and Aromatic Plants XI;1999

5. (+)-Germacrene A Biosynthesis;Plant Physiology;1998-08-01

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