Author:
Nishikawa Masaru,Imai Kazuo,Soma Yuko
Abstract
The electron scavenging reaction with COS was studied in γ-irradiated supercritical butenes in the density range 0.24–0.48 g/cm3 at 170 ± 1°C and in the liquid phase at room temperature. G(CO)fi estimated by means of the 'square root' model at each density studied agreed within experimental accuracy with G(N2)fi obtained previously. In liquid butenes, G(CO)fi, as well as G(N2)fi, agreed with Gfi obtained by electrical measurements. Rate constants estimated from the reactivity parameters for reactions with COS were less than 1/10 of those with N2O at each density studied except at d = 0.48 g/cm3 in trans-2-butene.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
2 articles.
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