Additions covalentes de nucléophiles sur les pyrido-as-triazines

Author:

Plé Nelly,Turck Alain,Queguiner Guy

Abstract

Covalent addition of various nucleophiles to pyrido-as-triazines was studied and the σ-adduct structures were determined by NMR. A remarkable reactivity toward carbon nucleophiles has been highlighted for pyrido-as-triazines bearing a pyridinic nitrogen in the β position: only in the pteridine series has a similar reactivity been encountered. Complete regioselectivity of the nucleophilic attack on the pyridine nucleus peri to the triazine was observed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. ChemInform Abstract: Covalent Additions of Nucleophiles to Pyrido-as-triazines.;ChemInform;2010-08-20

2. Volume 7 References;Comprehensive Heterocyclic Chemistry II;1996

3. Bicyclic 6-6 Systems: Four Heteroatoms 1:3;Comprehensive Heterocyclic Chemistry II;1996

4. Six-Membered Ring Systems: Triazines, Tetrazines and Fused Ring Polyaza Systems;A Critical Review of the 1993 Literature Preceded by Two Chapters on Current Heterocyclic Topics;1994

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