Author:
Bailey R. A.,Peterson Terry Roy
Abstract
Fe(thiourea)2(SCN)2, Fe(thiourea)4Cl2, and FeL2Cl2 (where L = methylthiourea, 1,3-dimethylthiourea, and 1,3-diethylthiourea) have been prepared and characterized. Magnetic moments and ligand field spectra indicate that all are octahedral. Infrared spectra show that the thiourea and methylthiourea ligands coordinate through the sulfur atom; the other two ligands are probably sulfur bonded also. The thiocyanate ion is coordinated through the nitrogen.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
39 articles.
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