Abstract
Mössbauer parameters for triphenyltin chloride and a number of its adducts with oxygen-donating Lewis bases are reported. The isomer shifts for all the compounds reported are constant within experimental error (1.29 ± 0.03 mm s−1, relative to SnO2). An approximate correlation between quadrupole splitting and the shift in element–oxygen stretching frequency between neat and complexed base is noted. This suggests that in general for these adducts, larger quadrupole splittings are associated with stronger complexes.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
21 articles.
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