Preparation of benzocyclobutenols by low temperature reaction of ketone enolates with benzynes-Reference-Cited by-同舟云学术

Preparation of benzocyclobutenols by low temperature reaction of ketone enolates with benzynes

Published:2003-09-01 Issue:9 Volume:81 Page:997-1002
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Tripathy Sasmita,Reddy Ranga,Durst Tony

Abstract

The reaction of benzynes, generated from halobenzenes with lithium tetramethylpipiperide (LTMP) at 40 to 78 °C, with ketone enolates affords benzocyclobutenols in fair to good yields.Key words: benzyne, ketone enolates, anthracenes, benzocyclobutenol, alkoxides.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v03-099

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