Abstract
The pyrolysis of HgMe2 has been investigated in a benzene carrier system using temperatures from 693 °K to 800 °K and pressures from 0.36 cm to 26.0 cm. High-pressure limiting rate constants were obtained above approximately 10 cm pressure. The high-pressure activation energy, E0, of 53.7 ± 0.5 kcal/mole is identified with D(MeHg—Me) within the limits D < E0 < D + RT.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
23 articles.
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