Author:
Rabinovitch B. S.,Winkler C. A.
Abstract
The Arrhenius constants have been evaluated for the hydrolysis of formamide, acetamide, propionamide, and benzamide in hydrochloric acid solutions over the concentration range 1 to 10 N. There is approximate correspondence between reaction rates and activation energies for the series of amides. An increase in observed activation energy with increasing acid concentration was found for all amides. The maximum in rate of hydrolysis, which occurs at higher acid concentrations, is discussed and accounted for by the variation in the Arrhenius constants with acid concentration.
Publisher
Canadian Science Publishing
Subject
Pharmacology (medical),Complementary and alternative medicine,Pharmaceutical Science
Cited by
14 articles.
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