Abstract
Dehydration of thiodiglycol at 195°–230° with potassium hydroxide produced a 36% yield of divinyl sulphide, 9–10% of 2-methyl-1,3-thioxolane, 7–8% of 1,4-thioxane, and 3.5% of vinyl 2-hydroxyethyl sulphide. Physical properties and infrared spectra are reported. Divinyl sulphide of high purity for polymer work was obtained by distillation in a Podbielniak column. Precautions that must be observed in the preparation, distillation, and storage are given.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
18 articles.
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