Affiliation:
1. Department of Chemistry, University of British Columbia, Vancouver, BC V6T 1Z1, Canada.
Abstract
Treatment of Mes*P=C(Si(CH3)3)Br with CH2=CHMgBr in the presence of Pd(0) affords 1-phosphabutadiene Mes*P=C(Si(CH3)3)–CH=CH2 (1) selectively as the Z isomer. Remarkably, treatment of Z-1 with n-BuLi (0.1 equiv.) resulted in quantitative formation of E-1. The exact role of the n-BuLi is unknown; however, it appears to be required to promote the isomerization in the absence of light. The isomerization of Z-1 to E-1 was also mediated by sunlight with the reaction mixture consisting of a ca. 1:9 ratio of Z-1 to E-1. DFT calculations were consistent with the thermodynamic favorability of the isomerization of Z-1 to E-1.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
1 articles.
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