C3 Symmetric oxazolinyl ligand as catalyst in the enantioselective addition of diethylzinc to aldehydes-Reference-Cited by-同舟云学术

C3 Symmetric oxazolinyl ligand as catalyst in the enantioselective addition of diethylzinc to aldehydes

Published:1997-06-01 Issue:6 Volume:75 Page:629-633
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Chan T.H.,Zheng G.Z.

Abstract

The C3 symmetric oxazolinyl ligand 1 has been synthesized. Compound 1 catalyzed the addition of diethylzinc to aromatic aldehydes to give secondary alcohols with high enantiomeric excesses (up to 90%). Keywords: diethylzinc, enantioselective synthesis, C3 symmetric ligands, enantioselective addition reactions, oxazolinyl ligands.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v97-076

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