Studies on the reaction of nitric oxide with α,β-unsaturated hydrazones-Reference-Cited by-同舟云学术

Studies on the reaction of nitric oxide with α,β-unsaturated hydrazones

Published:2012-06 Issue:6 Volume:90 Page:510-516
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Yang Desuo¹,Luo Xiaolin¹,Zhu Haiyun¹,Guo Yaning¹,Wu Longmin²

Affiliation:

1. Department of Chemistry & Engineering, Baoji University of Arts & Science, Baoji, 721013, P.R. China.

2. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China.

Abstract

α,β-Unsaturated arylhydrazones (1) reacted with nitric oxide (NO) in the presence of a trace of oxygen to give α- (2a–2c, 2e, and 2f) or β-nitro (2d and 2g) unsaturated hydrazones in good yield and with high stereoselectivity. The reaction occurs most likely by an electrophilic addition of NO2 to the carbon–carbon double bond of 1 at its α- or β-position.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v2012-022

Reference39 articles.

1. Chemistry of the Nitric Oxide-Releasing Diazeniumdiolate (“Nitrosohydroxylamine”) Functional Group and Its Oxygen-Substituted Derivatives

2. Chemistry of Nitric Oxide Relevant to Biology

3. Nitric Oxide Reacts with Methoxide

4. C-Nitroso Donors of Nitric Oxide

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