KINETICS OF THE REACTION H + CH4 = CH3 + H2-Reference-Cited by-同舟云学术

KINETICS OF THE REACTION H + CH4 = CH3 + H2

Published:1954-07-01 Issue:7 Volume:32 Page:650-659
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Berlie M. R.,Roy D. J. Le

Abstract

The reaction H + CH4 = CH3 + H2 has been studied in the temperature range 99° to 163 °C. The rate constant is given by the expression k = 1.7 × 10−14 exp (−4500/RT). The data are in agreement with the results, but not the interpretations, of previous work. The entropy of the methyl radical has been calculated for several temperatures.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v54-086

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