Author:
Ayer W. A.,Berezowsky J. A.,Law D. A.
Abstract
Monobromination of lycopodine hydrobromide in chloroform yields 6α-bromolycopodine hydrobromide, which can be epimerized to 6β-bromolycopodine hydrobromide. Hydrolysis of 6α-bromolycopodine proceeds with overall retention of configuration to give 6 α-hydroxylycopodine, which is identical with the Lycopodium lucidulum alkaloid L.20. On the basis of some of the rotatory dispersion data presented it is suggested that positively charged nitrogen has a negative specific rotativity.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
38 articles.
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