Abstract
The solvolysis of 1-14C-1-propylmercuric perchlorate in 10% dioxane –90% H2O, HOAc, or HCOOH gave, respectively, about 0.6, 2.5, or 3.5% isotopic scramblings, the rearranged 14C-label being distributed approximately equally over C-2 and -3. The results are considered in relation to protonated cyclopropanes as possible intermediates.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
7 articles.
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