Reactions of Sodium N,N-Diethyldithiocarbamate with the Chlorides and Bromides of Niobium(V), Tantalum(V), and Protactinium(V)-Reference-Cited by-同舟云学术

Reactions of Sodium N,N-Diethyldithiocarbamate with the Chlorides and Bromides of Niobium(V), Tantalum(V), and Protactinium(V)

Published:1971-04-15 Issue:8 Volume:49 Page:1151-1160
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Heckley P. R.,Holah D. G.,Brown D.

Abstract

Reactions between niobium(V), tantalum(V), and protactinium(V) chlorides and bromides and sodium N,N-diethyldithiocarbamate (Nadtc) have been examined in non-aqueous, non-oxygenated organic solvents. Complexes obtained are of the types Mdtc4X, Mdtc3X2, Mdtc3S, Mdtc2X3, and Mdtc2X3.nC6H6 (n = 0.7–1.0); not all complexes have been isolated for each metal. Within each group the niobium(V) and tantalum(V) complexes are isostructural; possible structures are discussed in the light of results from infrared (i.r.) and nuclear magnetic resonance (n.m.r.) spectra, molecular weight, and electrical conductivity measurements.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v71-191

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