Author:
Habeeb Jacob J.,Neilson Lynn,Tuck Dennis G.
Abstract
Vanadium metal dissolves rapidly in a cell Pt/X2 in CH3CN/V (anode) (X = Cl, Br, I) under applied voltages of 5–50 V. The solution phase yields crystalline VCl2. 2CH3CN, VBr2. CH3CN, or VI2; the acetonitrile adducts decompose to VX2 on heating in vacuo. Overall yields of VX2, based on weight of metal dissolved, are 80–90%.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
22 articles.
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