The oxidation of ortho-anisidine in alkaline medium. A product characterization and an EPR study
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Published:1994-05-01
Issue:5
Volume:72
Page:1351-1356
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ISSN:0008-4042
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Container-title:Canadian Journal of Chemistry
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language:en
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Short-container-title:Can. J. Chem.
Author:
Bolognese Adele,Buonanno Marina,Cantilena Antonio,Musci Giovanni,Alberti Angelo
Abstract
Alkaline oxidation of ortho-anisidine by potassium ferricyanide in alkaline aqueous solution was examined. Azo compounds, a diamine, and para-iminoquinones were isolated from the highly coloured reaction mixture. The reaction was also carried out within the cavity of an EPR spectrometer and two radical species have been detected. Following these product results and EPR studies, a radical mechanism is proposed for the process.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
4 articles.
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1. Potassium Ferricyanide;Encyclopedia of Reagents for Organic Synthesis;2007-03-15
2. Photochemical behavior of some substituted benzophenoxazinones;Journal of Heterocyclic Chemistry;1995-05
3. 12.2.5 Diaryl nitroxides;Landolt-Börnstein - Group II Molecules and Radicals
4. 12.2.3 Aryl nitroxides;Landolt-Börnstein - Group II Molecules and Radicals