Author:
Gruner Anthony C.,Thompson William T.
Abstract
Thermodynamic properties of silver chloride in molten silver chloride – lithium chloride – potassium chloride melts were studied using a silver chloride formation cell employing a chlorine electrode of novel design which facilitated measurements in ternary melts. The data were treated by analytical methods resulting in the generation of activity and the partial molar excess free energy at 500 °C.The measured properties were interpreted with the aid of a model which presupposed the existence of free silver ions as well as those "bonded" to adjacent chloride ions. With three adjustable parameters it was possible to account for the thermodynamic behavior of silver chloride.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
12 articles.
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