Abstract
An unusually large long-range hyperfine coupling to γ-phosphorus has been observed in nitroxide 2. The magnitude of the coupling is ascribed to the rigidity of the ring system and the consequent importance of conformations like 7. The radical forms upon lengthy exposure of 1 to air. It may also be prepared by standard methods, and is stable over a period of months at 0 °C. Transient and as yet unidentified radicals are observed during the oxidation of 1 to 2 with aryl peracids.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
6 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献