Author:
Oxton Ian A.,McInnes A. Gavin,Walter John A.
Abstract
1H nmr spectroscopy has been used to demonstrate hydrogen–deuterium exchange in solutions of NaBH4/NaB2H4 in diglyme and KBH4/KB2H4 in 18-crown-6 ether/chloroform. Earlier observations of such exchange with LiBH4/LiB2H4 in an ethereal solvent were confirmed. Spectra were simplified by broadband decoupling of deuterium, facilitating quantitative measurement of the degree of exchange.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
13 articles.
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