The chemical interpretation and the temperature dependence of the 14N nuclear quadrupole resonance of aniline and several derivatives

Author:

Yim C. T.,Whitehead M. A.,Lo Donald H.

Abstract

The 14N nuclear quadrupole resonance frequencies of aniline, o- and p-phenylene diamine, and p-chloro-, p-bromo-, and p-iodo-aniline were measured with a super-regenerative oscillator over a temperature range from 77 to 292 °K. The temperature dependence is analyzed. The chemical interpretation of the quadrupole coupling constants and asymmetry parameters is described.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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