Retardation of Cd2+and Zn2+ discharge at the dropping mercury electrode by adsorbed phenyl substituted phosphonium cations-Reference-Cited by-同舟云学术

Retardation of Cd2+and Zn2+ discharge at the dropping mercury electrode by adsorbed phenyl substituted phosphonium cations

Published:1988-05-01 Issue:5 Volume:66 Page:1053-1058
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Anastopoulos A.,Christodoulou A.,Moumtzis I.

Abstract

The effect of adsorbed propargyltriphenyl- and vinyltriphenylphosphonium cations on the discharge of Cd2+ and Zn2+ at dropping mercury electrode is studied by direct current polarographic measurements. Adsorption characteristics are determined by capacitance measurements. The size parameters of the activated complex and the surfactant particles are derived and an elucidation of the mechanism of the inhibited reaction is attempted.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v88-174

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