Abstract
The emission band system at 6000 Å found in discharges in flowing NO2 and attributed to NO+ by Jausserant, Grillet, and Duffieux has been examined at high dispersion and shown to be due to the transition of E2Σ+ (a new level) → A2Σ+ (the upper state of the γ system) of the NO molecule. The rotational and vibrational analysis of the system is given. The band system corresponding to the transition D2Σ+ (upper state of the ε system of NO) → A2Σ+ at 11,000 Å has also been observed and its analysis is presented. The separate nature of the D2Σ+ state from the A2Σ+ state is thus supported. Some brief remarks on other band structures found in discharges in flowing NO2 are included.
Publisher
Canadian Science Publishing
Subject
Pharmacology (medical),Complementary and alternative medicine,Pharmaceutical Science
Cited by
45 articles.
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