The total synthesis of (+)-ryanodol. Part IV. Preparation of (+)-ryanodol from (+)-anhydroryanodol-Reference-Cited by-同舟云学术

The total synthesis of (+)-ryanodol. Part IV. Preparation of (+)-ryanodol from (+)-anhydroryanodol

Published:1990-01-01 Issue:1 Volume:68 Page:186-192
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Deslongchamps Pierre,Bélanger André,Berney Daniel J. F.,Borschberg Hans-Jürg,Brousseau Robert,Doutheau Alain,Durand Robert,Katayama Hajime,Lapalme Richard,Leturc Dominique M.,Liao Chun-Chen,MacLachlan Frederick N.,Maffrand Jean-Pierre,Marazza Fabrizio,Martino Robert,Moreau Claude,Ruest Luc,Saint-Laurent Louiselle,Saintonge Roger,Soucy Pierre

Abstract

This paper reports the transformation of (+)-anhydroryanodol (6) to (+)-ryanodol (7) by reductive cyclization of lactone epoxide derivatives 9 and 20 (Scheme 4). Keywords: anhydroryanodol, ryanodol, diterpene, synthesis, reductive cyclization.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v90-024

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