Author:
Ozin G. A.,Voet A. Vander
Abstract
Infrared spectra are reported for matrix isolated cobalt dinitrogen isotopic species, Co14N2, Co14N15N and Co15N2, formed in the cocondensation reaction of atomic cobalt with dilute nitrogen–argon matrices at 10°K. The data provide the first unambiguous spectroscopic evidence for a dinitrogen molecule bonded in a "sideways" fashion to a transition metal atom.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
67 articles.
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