Author:
Currie G. N.,Ramsay D. A.
Abstract
The 4875 Å band of glyoxal has been photographed in absorption under high resolution and a rotational analysis carried out. The band is of type C and the principal molecular constants are: A′ = 0.9069 cm−1, B′ = 0.1983 cm−1, C′ = 0.1627 cm−1, A″ = 0.8910 cm−1, B″ = 0.2066 cm−1, C″ = 0.1681 cm−1, v0 = 20 507.57 cm−1. The A-rotational constants are smaller by a factor of ~2 than the constants found earlier for trans glyoxal. The new results are consistent with the assignment of the band to an allowed 1B1–1A1 (π*–n) transition of cis glyoxal. Temperature studies indicate that the cis isomer lies 1125 ± 100 cm−1 above the trans isomer. This is the first time that cis glyoxal has been detected experimentally.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
157 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献