Author:
Flood E. A.,Heyding R. D.
Abstract
From thermodynamic considerations a simple equation is derived which correlates length changes of a porous rigid adsorbent with its elastic and adsorptive properties. The equation contains a structure factor which is a constant characteristic of the adsorbent. Calculated and observed results agree reasonably well and suggest that, in the cases concerned, the assumptions underlying the derivation of the equation are valid. The underlying assumptions are: (a) both adsorbate and adsorbent can each exist separately in equilibrium with externally applied forces in states that are thermodynamically identical with their states in the adsorbate–adsorbent system, (b) adsorption isotherms represent paths of thermodynamic reversibility.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
49 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献