Author:
Adam Michael J.,Hall Laurance D.
Abstract
Metal-complexing, salicylaldimine ligands 4, 7, 8, and 9 have been synthesized from 2-amino-2-deoxy-D-glucopyranose and some of its derivatives with salicylaldehyde and 3-formyl-2-hydroxybenzoic acid. Copper(II), zinc, and cobalt(II) complexes were formed from ligand 7, whereas only copper(II) would complex with ligand 8. The sugar ligand 4 forms a water-soluble complex with copper(II) and ligand 9 forms a binuclear copper(II) complex. These products have been studied by 1H nmr, visible absorption, and esr spectroscopy, mass spectrometry, and by their magnetic moment data.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
47 articles.
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