Author:
Steinberger Hans-Uwe,Bauch Christian,Müller Thomas,Auner Norbert
Abstract
A metal-free catalytic intramolecular hydrosilylation reaction is reported. The key intermediates in the catalytic cycle are silyl cationic species. The reaction is used to produce 2-silanorbornanes 2 from 3-cyclopentenemethylsilanes 1 under mild conditions and in high isolated yields.Key words: hydrosilylation, catalysis, silaheterocycles, silyl cations.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
22 articles.
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