Author:
Betts R. H.,Dahlinger Olive F.
Abstract
A radio tracer method has been used to measure the heat and entropy of association of all the lanthanide ions (except promethium) with the chelating agent EDTA. Entropy terms are largely responsible for the remarkable stability of these complex ions. The results suggest, but do not prove, that a change in configuration of the complex occurs after gadolinium (element 64).
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
81 articles.
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