Abstract
The infrared and proton magnetic resonance spectra of α- and β-parachloral have been investigated and the dipole moment of α-parachloral has been determined. The results show that both isomers have the chair configuration of the ring and that α-parachloral has symmetry CS, with one axial and two equatorial CCl3 groups and that β-parachloral has symmetry C3v with three equatorial CCl3 groups.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
23 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. The structure of α-parabutylchloral;Recueil des Travaux Chimiques des Pays-Bas;2010-09-02
2. C3S3Ring Systems;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
3. The boat conformation of ?-parachloral. Notes on the revised structures of ?- and?-parachloral;Journal of Crystallographic and Spectroscopic Research;1986-04
4. Isomerism in parabutylchloral; x-ray crystallographic determinations of 2,4,6-tris(1?,1?,2?-trichloropropyl)-1,3,5-trioxanes;Journal of Crystallographic and Spectroscopic Research;1985-08
5. The structures of α- and β-parachloral [2,4,6-tris-(trichloromethyl)-1,3,5-trioxane];Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry;1980-10-01